What is molybdenum silicide and its properties?

What is molybdenum Silicide? Molybdenum Silicide This gray metallic solid is an inorganic chemical compound with the formula MoSi2. It is insoluble, except in nitric or hydrofluoric acid. The two atoms have similar radii, the electronegativity and properties are close. It is electrically conductible and forms an oxidation-resistant silica passivation film on the surface of molybdenum silicide at high temperatures. It can be used for high-temperature coatings, electric heating components, integrated electrode film, structural materials and as reinforcing agent for composite materials.

Preparation and use of molybdenum Silicide
MoSi2 is formed by the direct reaction between two elements, Mo & Si. Reaction formula
Mo+2Si-MoSi2
Molybdenum Silicide: Physicochemical Properties
MoSi2 (also known as Dalton type intermetallic compound) is the intermediate phase in the MoSi binary alloy with the highest silicon contents. It combines both the metal and ceramic properties and has an excellent high-temperature performance. It has a good high-temperature resistance to oxidation, with an oxidation temperature above 1600 that is comparable to SiC. It also has a moderate density (6.24g/cm3), a low coefficient of thermal contraction (8.1×10-6K-1), good electrical and thermal conduction, and brittle transition temperatures (1000) just below ceramic-like hardness. MoSi can be used as an anti-oxidation coating for high temperatures, a heating element and structural material.
MoSi2 has molybdenum bonded with silicon via metallic bonds while silicon is bonded covalently to silicon. It is not soluble with mineral acids, including aqua regia. However, it is soluble with a mixture containing nitric and hydrofluoric acids.
In an oxidizing environment, dense quartz glass (SiO2) is formed on the surface of the molybdenum silicide to protect it from continuous oxidation. When the heating element temperature exceeds 1700 degrees, the SiO2 protective films are formed, thickening up to 1710 degrees and fusion of SiO2 into molten drops. Surface extension causes the loss of protective capability. It is possible to form a protective layer again when an element is used continuously with an oxidizing substance. Due to strong oxidation, the element can’t be used at temperatures between 400 and 700degC for a prolonged period of time.

Applications of molybdenum Silicide
In the following industries, molybdenum silicide is used as a high-temperature coating material, an electric heating element, an integrated electrode film and structural materials. It can also be found in composite materials that are reinforced, materials resistant to wear, materials for joining structural ceramics etc.
1) Energy and chemical industries: high-temperature thermocouples (and their protection tubes), melting vessel crucibles.
2) Microelectronics Industry: MoSi2 & other refractory metallic silicides (Ti5Si3, TaSi2, TaSi2, TaSi2, TiSi3, etc.) These films are ideal for interconnecting lines and large-scale circuit gates.
(3) Aerospace Industry: It is extensively researched and widely used as anti-oxidation high temperature coating material. Specially for turbine engine parts, including blades, impellers combustors tailpipes and sealing devices.
(4) Automotive: turbo engine supercharger, valve body and spark plug for automobiles.

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The Applications of Molybdenum Silicide

What is it? Molybdenum Silicide ? Molybdenum Disilicide, an organic compound that has the chemical name MoSi2, can be described as a gray metallic solid. Although insoluble in most acids it is soluble in hydrofluoric acid and nitric. The radii of these two atoms do not differ much, and their electronegativities are very close. They also have properties that are similar to metals and ceramics. Molybdenum Disilicide can be used as an electrically conducting material. A passivation layer made of silicon dioxide can also be created on the surface at high temperatures to prevent further oxidation. It is used to make high temperature antioxidation coating materials, integrated electrode film, structural materials and reinforcing agents in composite materials.
Molybdenum Siicide:
MoSi2 (intermediate phase) is the most silicon-rich in the Mo–Si binary alloy system. It’s a Dalton type intermetallic compound of a fixed composition. This high-temperature material has great performance because of its dual properties of metal and ceramic. Excellent high temperature resistance to oxidation, it has a oxidation resistant temperature of 1600. This is equivalent in SiC. It also has a moderate density (6.24g/cm3), low thermal expansion coefficient (8.10-6K-1), good electrical conductivity, high brittle-ductile temperature (1000 ) and is below ceramic-like hardbrittleness. Above 1000, MoSi is soft and plastic-like metal. MoSi can be used in integrated circuits, heating elements and high temperature antioxidation coatings.
MoSi2 consists of silicon and molybdenum bonded with metal bonds. In MoSi2, silicon and molybdenum are bonded via covalent bonds. Molybdenum Disilicide is a gray tetragonal crystalline. It is insoluble within common mineral acids (including aqua regia), however, it can be dissolved in mixed acids of hydrofluoric and nitric acids. It can be used to heat elements in high-temperature (1700) environments due to its high resistance to high-temperature oxygenation.
An oxidizing atmosphere forms a protective layer on the dense quartz (SiO2) surface. This prevents continuous oxidation and deterioration of molybdenum disilicide. SiO2 fused to form protective films when temperatures exceed 1700°C. It loses its protective power due to the act of expanding its surface. The oxidant acts on the element and forms a protective film. It is important to note that this element can not be used for prolonged periods in temperatures between 400 and 700 degrees C due to its strong oxidation at lower temperatures.
Molybdenum Silicide Properties
Other Titles molybdenum disilicide (MoSi2 Powder)
No. 12136-78-6
Combination Formula MoSi2
Molecular Weight 152.11
Appearance Gray to Black Powder
Melting Point 1900-2050 degC
Boiling Point N/A
Density 6.23-6.31 g/cm3
Solubility of H2O N/A
Electrical Resistivity 0.0000270 – 0.0000370 ohm-cm
Specific heat 0.437 J/g-degC (23 degC)
Tensile Strength 185 MPa
Thermal Conductivity 66.2 W/m-K (23 degC)
Thermal Expansion N/A
Vickers Hardness 900-1200
Young’s Modulus N/A
Exact 153.859261
Molybdenum Silicon MoSi2 MoPowder CAS 12136-876-6
Molybdenum Silicide:
Molybdenum disilicide can be used in high-temperature anti-oxidation coatings, electric heating elements and integrated electrode films.
1. Energy chemical industry: Electric heating elements, high heat exchangers of nuclear reactor devices, gas burners. High temperature thermocouples with their protective tubes. Melting vessels and crucibles are used to melt sodium, lithium and lead.
2. MoSi2 and other reactive metal silicides, such as WSi2, TaSi2, Ti5Si3, WSi2, TaSi2, etc. are used in the microelectronics sector. are key candidate materials for large-scale integrated gate and interconnect film production.
3. Aerospace industry. It has been extensively and thoroughly researched and successfully applied as a high temperature antioxidation coating material. This material is especially useful for components of turbine engines such as blades or impellers.
4. Automobile industry: engine parts, turbocharger rotors and valve bodies for automobiles.
Molybdenum Silicide’s main supplier
Tech Co., Ltd. () is a professional silicide powder Over 12 years’ experience in chemical products development and research. We accept credit cards, T/T and West Union payments. We will ship goods overseas via FedEx, DHL and by air or sea to our customers.
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